Aluminum is a widely used material known for its lightweight, strength, and versatility. However, its structural properties undergo significant changes when subjected to elevated temperatures. This post will explore what happens to aluminum when exposed to temperatures exceeding 400°F (204°C).


1. Loss of Strength (Softening)

  • Aluminum alloys begin to lose their strength above 300°F (149°C).
  • At 400°F, yield and tensile strength decrease noticeably, making the material less capable of withstanding mechanical loads.
  • Prolonged exposure at these temperatures can lead to creep deformation, where the material slowly deforms under constant stress.

2. Thermal Expansion

  • Aluminum has a high coefficient of thermal expansion (~23.1×10−6 /°F23.1 \times 10^{-6}\, /°F).
  • As the temperature rises, aluminum expands significantly, leading to thermal stresses or misalignment, especially in assemblies involving materials with different expansion rates.

3. Changes in Elasticity

  • The modulus of elasticity decreases with increasing temperature, making aluminum more ductile.
  • This reduction means the material is less deformation-resistant, increasing the risk of structural failure under load.

4. Recrystallization and Microstructural Changes

  • High temperatures can cause recrystallization, leading to grain growth and coarsening of the microstructure.
  • These changes reduce fatigue strength and toughness, impacting the material’s durability.

5. Oxidation

  • Aluminum naturally forms a protective oxide layer, but elevated temperatures accelerate the oxidation process.
  • This can alter surface properties and, in some cases, reduce the material’s structural integrity over time.

6. Thermal Stress Fatigue

  • Repeated heating and cooling cycles can induce thermal stress, leading to fatigue failure over time.
  • This is especially critical in environments where temperature fluctuations are typical.

7. Specific Alloy Behavior

  • Different aluminum alloys respond differently to high temperatures:
    • 6xxx series (e.g., 6061): Exhibits softening but retains good corrosion resistance.
    • 7xxx series (e.g., 7075): More prone to stress-corrosion cracking.
  • Alloys with higher silicon, magnesium, or copper content may perform better in elevated temperatures but degrade over time.

Conclusion

When exposed to temperatures above 400°F (204°C), aluminum undergoes significant changes in strength, elasticity, and microstructure, making it less suitable for structural applications. Prolonged exposure or repeated thermal cycling exacerbates these effects.

For applications requiring high-temperature performance, consider using specially designed aluminum alloys or alternative materials that can maintain their properties under such conditions.

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